Conclusive evidence of the trapping of primary ozonides.
نویسندگان
چکیده
[reaction: see text] Anomalous ozonolysis of strained bicyclic allylic alcohols yields alpha-hydroxymethyl ketones. The proposed mechanism involves an unusual trapping of the primary ozonide that undergoes a Grob-like fragmentation instead of dissociating into the Criegee intermediates.
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ورودعنوان ژورنال:
- Organic letters
دوره 3 4 شماره
صفحات -
تاریخ انتشار 2001